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CHANGE OF BORIDE IN Fe_(70)Cr_(18)Mo_2SiB_9 WITH THERMAL TREATMENT

LIN Yijian HU Jian YOU Yunlong JING Chunyong YU Quanqin Shanghai Iron and Steel Research Institute , Shanghai , China LIN Yijian Measuring and Testing Centre , Shanghai Iron and Steel Research Institute , Shanghai 200940 , China

金属学报(英文版)

The formation of borides M_3B_2 M_2B_2 and M_(23)B_6 may be carried out from the melt-quenched Fe_(70)Cr_(18)Mo_2SiB_9 during 700—1150℃ annealing.As the temperature raising,the M_2B,the majority being Fe_2B.may be gradually replaced by Cr_2B via the co-existence between Fe_2B and Cr_2B.The Cr_2B may be formed by trans formation of Fe_2B through the atomic substitu- tion and structural adjustment.The thin slice of remaining Fe_2B is sandwiched between(100) faces of(Cr,Fe)_2B as stacking fault.The M_2B_2 is virtually composed of the Mo_(1+x)(Fe,Cr)_(2-x)B_2 where x(0≤x≤1)increases with the increase of temperature.

关键词: FeCrMoSiB alloy , null , null , null

Fe_(70)Cr_(18)Mo_2SiB_9中硼化物的变化规律

林一坚 , 胡坚 , 尤云龙 , 井春永 , 郁泉琴

金属学报

液态急冷Fe_(70)Cr_(18)Mo_2SiB_2在700—1150℃退火中可生成M_2B,M_3B_2和M_(23)B_6硼化物。M_2B随温度的升高,由Fe_2B为主,经Fe_2B和Cr_2B的平衡共存,逐步被Cr_2B所取代。Cr_2B可由Fe_2B通过原子置换和结构调整转变而成,残余Fe_2B以层错形式的薄片夹在(Cr,Fe)_2B(100)面之间,M_3B_2实际为Mo_(1+x)(Fe,Cr)_(2-x)B_2(0≤x≤1),x随温度上升而连续增大。

关键词: FeCrMoSiB合金 , M_2B , M_3B_2 , M_(23)B_6

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